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We mentioned previously that the hydration of alkenes required a strong acid as a catalyst, because water itself is too weak an acid to initiate the proton-transfer step. However, if a small amount of a strong acid such as sulfuric acid is present, hydronium ions, H3O⊕, are formed in sufficient amount to protonate reasonably reactive alkenes, although by no means as effectively as does concentrated sulfuric acid. The carbocation formed then is attacked rapidly by a nucleophilic water molecule to give the alcohol as its conjugate acid, which regenerates hydronium ion by transferring a proton to water. The reaction sequence follows for 2-methylpropene:
In this sequence, the acid acts as a catalyst because the hydronium ion used in the proton addition step is regenerated in the final step.
Sulfuric acid (or phosphoric acid) is preferred as an acid catalyst for addition of water to alkenes because the conjugate base, HSO4− (or H2PO4−), is a poor nucleophile and does not interfere in the reaction. However, if the water concentration is kept low by using concentrated acid, addition occurs to give sulfate (or phosphate) esters. The esters formed with sulfuric acid are either alkyl acid sulfates R−OSO3H or dialkyl sulfates (RO)2SO2. In fact, this is one of the major routes used in the commercial production of ethanol and 2-propanol. Ethen and sulfuric acid give ethyl hydrogen sulfate, which reacts readily with water in a second step to give ethanol:
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