What causes this signal splitting, and what useful information can be obtained from it ? |
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What causes this signal splitting, and what useful information can be obtained from it ?
If an atom under examination is perturbed or influenced by a nearby nuclear spin (or set of spins), the observed nucleus responds to such influences, and its response is manifested in its resonance signal. This spin-coupling is transmitted through the connecting bonds, and it functions in both directions. Thus, when the perturbing nucleus becomes the observed nucleus, it also exhibits signal splitting with the same J. For spin-coupling to be observed, the sets of interacting nuclei must be bonded in relatively close proximity (e.g. vicinal and geminal locations), or be oriented in certain optimal and rigid configurations. Some spectroscopists place a number before the symbol J to designate the number of bonds linking the coupled nuclei (colored orange below). Using this terminology, a vicinal coupling constant is 3J and a geminal constant is 2J.
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دراسة: عدم ترتيب الغرفة قد يدل على مشاكل نفسية
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علماء: تغير المناخ تسبب في ارتفاع الحرارة خلال موسم الحج
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عمره عام واحد ويعاني من ورم خبيث بوزن (3) كغم وعلى نفقة العتبة الحسينية ... مستشفى خديجة الكبرى (ع) ينجح باستئصال ورم سرطان الكلى لطفل من محافظة الأنبار
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