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Bond Order

المؤلف:  University of Missouri System

المصدر:  Introductory chemistry

الجزء والصفحة:  .................

13-11-2020

2773

Bond Order

We have just seen that the bonding molecular orbital is lower energy and promotes the formation of a covalent bond, while the antibonding molecular orbital is higher energy with a node of zero electron density between the atoms that destabilizes the formation of a covalent bond. We can evaluate the strength of a covalent bond by determining its bond order.

Bond order = 1/2 (# of electrons in bonding MOs – # of electrons in antibonding MOs)

Bond-order values can be whole numbers, fractions, or zero. These values correspond to the valence bond model, so a bond order of 1 is equal to a single bond, and 2 is equal to a double bond. A value of zero means that there is no bond present, and the atoms exist separately.